Lanthanide Complexes Containing a Terminal Ln═O Oxo Bond: Revealing Higher Stability of Tetravalent Praseodymium versus Terbium.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00525
Abstract: We report on the reactivity of gas-phase lanthanide-oxide nitrate complexes, [Ln(O)(NO3)3]- (denoted LnO2+), produced via elimination of NO2• from trivalent [LnIII(NO3)4]- (Ln = Ce, Pr, Nd, Sm, Tb, Dy). These complexes feature a LnIII-O• oxyl,… read more here.
Keywords: stability tetravalent; bond; oxo bond; higher stability ... See more keywords
Is the protactinium(V) mono-oxo bond weaker than what we thought?
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc04522j
Abstract: The bond distance is the simplest and most obvious indicator of the nature of a given chemical bond. However, for rare chemistry, it may happen that it is not yet firmly established. In this communication,… read more here.
Keywords: bond weaker; oxo bond; weaker thought; mono oxo ... See more keywords