Recent progress on exploring µ-oxo bridged binuclear porphyrinoid complexes in catalysis and material science
Sign Up to like & getrecommendations! Published in 2019 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2019.03.016
Abstract: Abstract This review covers recent advances in the preparation, characterization and application of µ-oxo dimeric complexes with different metals and non-metal and macrocyclic ligands achieved during last ten years. Binuclear iron, manganese, ruthenium, chromium, molybdenum,… read more here.
Keywords: exploring oxo; oxo bridged; bridged binuclear; progress exploring ... See more keywords
Effect of 3d/4p Mixing on 1s2p Resonant Inelastic X-ray Scattering: Electronic Structure of Oxo-Bridged Iron Dimers.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c11193
Abstract: 1s2p resonant inelastic X-ray scattering (1s2p RIXS) has proven successful in the determination of the differential orbital covalency (DOC, the amount of metal vs ligand character in each d molecular orbital) of highly covalent centrosymmetric… read more here.
Keywords: resonant inelastic; oxo bridged; 1s2p rixs; edge ... See more keywords
First crystal structures of oxo-bridged [CrIIITaV] dinuclear complexes: spectroscopic, magnetic and theoretical investigations of the Cr–O–Ta core
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj01493k
Abstract: Heterodinuclear complexes [Cr(bpy)2(H2O)(μ-O)Ta(C2O4)3]2·3.5H2O (1) and [H2(terpy)][Cr(terpy)(C2O4)(μ-O)Ta(C2O4)3]·0.5H2C2O4·2.5H2O (2) (bpy = 2,2′-bipyridine; terpy = 2,2′:6′,2′′-terpyridine) have been synthesised through a reaction of a tris(oxalate)oxotantalate(V) anion and a complex chromium(III) cation with corresponding aromatic N-donor ligands. These are… read more here.
Keywords: oxo bridged; crystal structures; dft calculations; geometry ... See more keywords
Insights at the molecular level into the formation of oxo-bridged trinuclear uranyl complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06310c
Abstract: Reaction of 1,3,4,6-tetra-O-acetyl-N-(2-hydroxy)-naphthylidene glucosamine (HL(Ac)) with uranyl acetate in ethanol leads to formation of dinuclear [(UO2)2(L)2] (1). In a second step 1 is quantitatively transferred into the trinuclear oxo-bridged complex [(UO2)3(μ3-O)(L)3]2- (22-) via deprotonation and… read more here.
Keywords: level formation; insights molecular; oxo bridged; formation ... See more keywords
(Hydr)oxo-bridged heme complexes: From structure to reactivity
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Porphyrins and Phthalocyanines"
DOI: 10.1142/s1088424619300258
Abstract: Iron–porphyrins (i.e., hemes) are present throughout the biosphere and perform a wide range of functions, particularly those that involve complex multiple-electron redox processes. Some common heme... read more here.
Keywords: oxo bridged; complexes structure; hydr oxo; bridged heme ... See more keywords