Re-investigation of an octanuclear iron-oxo complex supported by 4- butyl-pyrazolido ligands
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.07.003
Abstract: Abstract The synthesis and characterization of the octanuclear all-ferric compounds [Fe8(μ4-O)4(μ-4-R-pz)12Cl4], R = tBu (1) and nBu (2) by spectroscopic (1H NMR, UV–Vis, FTIR, 57Fe-Mossbauer) and electrochemical methods are reported along with the single crystal X-ray structure… read more here.
Keywords: investigation octanuclear; iron oxo; supported butyl; octanuclear iron ... See more keywords
Computational Study on the Light-Induced Oxidation of Iridium-Aqua Complex to Iridium-Oxo Complex over WO3(001) Surface.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02704
Abstract: An iridium aqua complex [IrIII(η5-C5Me5){bpy(COOH)2}(H2O)]2+ under visible light irradiation has been experimentally reported to form an iridium-oxo (Ir-oxo) complex [IrV(η5-C5Me5){bpy(COOH)2}(O)]2+, which oxidizes H2O to O2. However, the mechanism for the formation of this Ir-oxo complex… read more here.
Keywords: oxo; light induced; iridium; oxo complex ... See more keywords
The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)-Oxo Complex.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c04919
Abstract: In this paper, we report the preparation, spectroscopic and theoretical characterization, and reactivity studies of a Co(IV)-oxo complex bearing an N4-macrocyclic coligand, 12-TBC (12-TBC = 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane). On the basis of the ligand and the structure… read more here.
Keywords: oxo; oxo complex; remains intact; spectroscopy ... See more keywords
Titanium(IV) Oxo-Complex with Acetylsalicylic Acid Ligand and Its Polymer Composites: Synthesis, Structure, Spectroscopic Characterization, and Photocatalytic Activity
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DOI: 10.3390/ma15134408
Abstract: The titanium oxo complexes are widely studied, due to their potential applications in photocatalytic processes, environmental protection, and also in the biomedical field. The presented results concern the oxo complex synthesized in the reaction of… read more here.
Keywords: photocatalytic activity; structure; acetylsalicylic acid; titanium oxo ... See more keywords
The Composites of PCL and Tetranuclear Titanium(IV)–Oxo Complex with Acetylsalicylate Ligands—Assessment of Their Biocompatibility and Antimicrobial Activity with the Correlation to EPR Spectroscopy
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma16010297
Abstract: In our research, we have focused on the biological studies on composite materials produced by the dispersion of titanium(IV)–oxo complex (TOC) with acetylsalicylate ligands in a poly(ε-caprolactone) (PCL) matrix, which is a biodegradable thermoplastic polymer… read more here.
Keywords: acetylsalicylate ligands; titanium oxo; spectroscopy; oxo complex ... See more keywords