Ligand Control of Oxidation and Crystallographic Disorder in the Isolation of Hexavalent Uranium Mono-Oxo Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04056
Abstract: The development of high-valent transuranic chemistry requires robust methodologies to access and fully characterize reactive species. We have recently demonstrated that the reducing nature of imidophosphorane ligands supports the two-electron oxidation of U4+ to U6+… read more here.
Keywords: crystallographic disorder; oxidation; oxo complexes; methodology ... See more keywords
Isolation of a Terminal Co(III)-Oxo Complex.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07399
Abstract: Late transition metal oxo complexes with high d-electron counts have been implicated as intermediates in a wide variety of important catalytic reactions; however, their reactive nature has often significantly limited their study. While some examples… read more here.
Keywords: oxo complexes; isolation terminal; oxo; metal oxo ... See more keywords
MnIV-Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for MnIV-oxo than FeIV-oxo species.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00308h
Abstract: Using the pentadentate ligand (N-bis(1-methyl-2-benzimidazolyl)methyl-N-(bis-2-pyridylmethyl)amine, 2pyN2B), presenting two pyridyl and two (N-methyl)benzimidazolyl donor moieties in addition to a central tertiary amine, new MnII and MnIV-oxo complexes were generated and characterized. The [MnIV(O)(2pyN2B)]2+ complex showed spectroscopic… read more here.
Keywords: oxo; mniv 2pyn2b; bis; oxo complexes ... See more keywords
Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes
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DOI: 10.1039/d1sc06623d
Abstract: This study presents the role of 5d orbitals in the bonding, and electronic and magnetic structure of Ce imido and oxo complexes synthesized with a tris(hydroxylaminato) [((2-tBuNO)C6H4CH2)3N]3− (TriNOx3−) ligand framework, including the reported synthesis and… read more here.
Keywords: 320 320; imido oxo; oxo complexes; state ... See more keywords
Differences in chemoselectivity in olefin oxidation by a series of non-porphyrin manganese(IV)-oxo complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00876a
Abstract: High valent metal-oxo intermediates are versatile oxidants known to facilitate both oxygen atom transfer (OAT) and hydrogen atom transfer (HAT) reactions in nature. In addition to performing essential yet challenging biological reactions, these intermediates are… read more here.
Keywords: oxidation; mniv oxo; chemoselectivity; oxo ... See more keywords