An investigation of ligand effects on the visible light-induced formation of porphyrin–iron(IV)-oxo intermediates
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DOI: 10.1039/c7nj03296j
Abstract: High-valent porphyrin–iron-oxo intermediates are the central oxidizing species in heme-containing enzymes and synthetic oxidation catalysts. In this work, we investigated a new photochemical entry to porphyrin–iron(IV)-oxo derivatives in a variety of porphyrin ligands with different… read more here.
Keywords: iron; porphyrin iron; oxo intermediates; iron oxo ... See more keywords
Oxidative dehalogenation of halophenols by high-valent nonheme iron(IV)-oxo intermediates.
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DOI: 10.1039/d1fd00064k
Abstract: Mononuclear high-valent iron(IV)-oxo intermediates are excellent oxidants towards oxygenation reactions by heme and nonheme metalloenzymes and their model systems. One of the most important functions of these intermediates in nature is to detoxify various environmental… read more here.
Keywords: iron; iron oxo; dehalogenation; oxo intermediates ... See more keywords