The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)-Oxo Complex.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c04919
Abstract: In this paper, we report the preparation, spectroscopic and theoretical characterization, and reactivity studies of a Co(IV)-oxo complex bearing an N4-macrocyclic coligand, 12-TBC (12-TBC = 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane). On the basis of the ligand and the structure… read more here.
Keywords: oxo; oxo complex; remains intact; spectroscopy ... See more keywords
Can you break the oxo-wall? A multiconfigurational perspective.
Sign Up to like & getrecommendations! Published in 2022 at "Faraday discussions"
DOI: 10.1039/d1fd00072a
Abstract: The concept of the "oxo-wall" was conceived about 60 years ago by Harry B. Gray, and has been found to be related to the non-existence of high-valent M-oxo species in the +IV oxidation state in… read more here.
Keywords: coiii; break oxo; oxo species; coiv coiii ... See more keywords