Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00384
Abstract: The two acentric aluminoborates (ABOs) [M(dap)3]2{Al[B5O7(OH)3][B5O8(OH)2][B6O9(OH)2]} (M and dap represent Co(1)/Ni(2) and 1,2-diaminopropane, respectively) templated by chiral metal complexes (CMCs) have been solvothermally synthesized. The isostructural 1 and 2 crystallize in the chiral space group… read more here.
Keywords: metal complex; wavelike layers; two chiral; chiral metal ... See more keywords
Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03846a
Abstract: Two new layered and porous-layered borates ([H2dap][B7O11(OH)] (1, dap = 1,2-propanediamine) and [H3O]K3.52Na3.48{Al2[B7O13(OH)][B5O10][B3O5]}[CO3] (2)) have been solvothermally made. 1 features a 2D layer made of the [B7O13(OH)]6- cluster, in which H2dap is located in the… read more here.
Keywords: novel; new layered; porous layered; oxoboron clusters ... See more keywords