Comparing the reactivity of an oxoiron(IV) cation radical and its oxoiron(V) tautomer towards C-H bonds.
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DOI: 10.1039/d2cc07005g
Abstract: An oxoiron(IV) cation radical is generated upon two-electron oxidation of an iron(III) complex bearing an electron-rich methoxy substituted bTAML framework and thoroughly characterized via multiple spectroscopic techniques and density functional theory (DFT). Reactivity studies demonstrate… read more here.
Keywords: comparing reactivity; oxoiron; cation radical; oxoiron cation ... See more keywords