Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics: kinetic, mechanistic and computational studies.
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DOI: 10.1039/c8dt03519a
Abstract: The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(iv) complexes and their precursor iron(ii) complexes with m-CPBA as the terminal oxidant. These models, including detailed… read more here.
Keywords: flavone synthase; oxoiron complexes; kinetic mechanistic; mechanistic computational ... See more keywords