Synthesis and thermal reactivity of a Me 3 N-stabilized cyclic (alkyl)(amino)oxophosphonium ion
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DOI: 10.1016/j.ica.2016.07.046
Abstract: Abstract Reaction of cyclic (alkyl)(amino)phosphorous chloride 3 with GaCl3 followed by the treatment with Me3NO afforded trimethylamine-stabilized oxophosphonium ion 5, which was fully characterized by NMR spectroscopy and X-ray diffraction analysis. Computational study using DFT… read more here.
Keywords: oxophosphonium ion; cyclic alkyl; oxophosphonium; alkyl amino ... See more keywords