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A Photocatalytic System Composed of Benzimidazolium Aryloxide and Tetramethylpiperidine 1-Oxyl to Promote Desulfonylative α-Oxyamination Reactions of α-Sulfonylketones

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Published in 2022 at "ACS Omega"

DOI: 10.1021/acsomega.1c06857

Abstract: A new photocatalytic system was developed for carrying out desulfonylative α-oxyamination reactions of α-sulfonylketones in which α-ketoalkyl radicals are generated. The catalytic system is composed of benzimidazolium aryloxide betaines (BI+–ArO–), serving as visible light-absorbing electron… read more here.

Keywords: system; desulfonylative oxyamination; oxyamination reactions; photocatalytic system ... See more keywords