Cascading g-C3N4 and Peroxygenases for Selective Oxyfunctionalization Reactions
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DOI: 10.1021/acscatal.9b01341
Abstract: Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry. Instead of relying on complicated electron transport chains, they rely on simple hydrogen peroxide as the stoichiometric oxidant. Their poor robustness against H2O2 can be addressed… read more here.
Keywords: c3n4; selective oxyfunctionalization; c3n4 peroxygenases; peroxygenases selective ... See more keywords
Repertoire of Computationally Designed Peroxygenases for Enantiodivergent C–H Oxyfunctionalization Reactions
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DOI: 10.1021/jacs.2c11118
Abstract: The generation of enantiodivergent biocatalysts for C–H oxyfunctionalizations is ever more important in modern synthetic chemistry. Here, we have applied the FuncLib algorithm based on phylogenetic and Rosetta calculations to design a diverse repertoire of… read more here.
Keywords: computationally designed; peroxygenases enantiodivergent; enantiodivergent oxyfunctionalization; oxyfunctionalization reactions ... See more keywords
Scalable biocatalytic C-H oxyfunctionalization reactions.
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DOI: 10.1039/d0cs00440e
Abstract: Catalytic C-H oxyfunctionalization reactions have garnered significant attention in recent years with their ability to streamline synthetic routes toward complex molecules. Consequently, there have been significant strides in the design and development of catalysts that… read more here.
Keywords: biocatalytic oxyfunctionalization; oxyfunctionalization; oxyfunctionalization reactions; scalable biocatalytic ... See more keywords