A general approach for the formation of oxygen-chelated ruthenium alkylidene complexes relying on the Thorpe–Ingold effect
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DOI: 10.1039/c8qo00160j
Abstract: Ruthenium alkylidene complexes are prepared via enyne ring-closing metathesis relying on the exo and endo gem-dialkyl substituent effect. The structural features stabilizing oxygen-chelates are explored and confirmed by single crystal X-ray diffraction analyses. In stark… read more here.
Keywords: oxygen; oxygen chelated; alkylidene complexes; chelated ruthenium ... See more keywords