Singlet Oxygen-Mediated Electrochemical Filter for Selective and Rapid Degradation of Organic Compounds
Sign Up to like & getrecommendations! Published in 2020 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.0c02223
Abstract: Singlet oxygen (1O2)-based homogeneous oxidation processes have been extensively investigated for selective degradation of organic substrates. Herein, to address the existing limitations of these h... read more here.
Keywords: singlet oxygen; oxygen mediated; mediated electrochemical; degradation organic ... See more keywords
Oxygen-Mediated Superexchange Interactions and Their Impact on the Structural Stability, Magnetic Order, and Magnetocrystalline Anisotropy of One-Dimensional Co-Oxide Chains on Rh(553) Step-Surfaces
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c07762
Abstract: First-principles calculations in the framework of the generalized gradient approximation together with U on-site Coulomb corrections in the GGA + U approach to density functional theory (DFT) are p... read more here.
Keywords: oxygen mediated; impact structural; interactions impact; superexchange interactions ... See more keywords
Molecular Oxygen-Mediated Radical Alkylation of C(sp3)-H Bonds with Boronic Acids.
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DOI: 10.1021/acs.orglett.1c00948
Abstract: A direct and site-specific alkylation of (sp3)C-H bond with aliphatic boronic acid was achieved. By simply heating glycinates and amines together with alkylboronic acids under an oxygen atmosphere, a variety of unnatural α-amino acids and… read more here.
Keywords: alkylation; molecular oxygen; alkylation sp3; oxygen mediated ... See more keywords
Singlet oxygen mediated iron-based Fenton-like catalysis under nanoconfinement
Sign Up to like & getrecommendations! Published in 2019 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.1819382116
Abstract: Significance In the bulk phase, hydroxyl radical from the one-electron transfer and high-valent iron-oxo species from the O-atom transfer compete to be the reactive intermediates in the Fenton and related reactions. In the confined space… read more here.
Keywords: oxygen mediated; fenton like; singlet oxygen; iron ... See more keywords