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Published in 2020 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.0c02223
Abstract: Singlet oxygen (1O2)-based homogeneous oxidation processes have been extensively investigated for selective degradation of organic substrates. Herein, to address the existing limitations of these h...
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Keywords:
singlet oxygen;
oxygen mediated;
mediated electrochemical;
degradation organic ... See more keywords
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Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c07762
Abstract: First-principles calculations in the framework of the generalized gradient approximation together with U on-site Coulomb corrections in the GGA + U approach to density functional theory (DFT) are p...
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Keywords:
oxygen mediated;
impact structural;
interactions impact;
superexchange interactions ... See more keywords
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Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00948
Abstract: A direct and site-specific alkylation of (sp3)C-H bond with aliphatic boronic acid was achieved. By simply heating glycinates and amines together with alkylboronic acids under an oxygen atmosphere, a variety of unnatural α-amino acids and…
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Keywords:
alkylation;
molecular oxygen;
alkylation sp3;
oxygen mediated ... See more keywords
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Published in 2019 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.1819382116
Abstract: Significance In the bulk phase, hydroxyl radical from the one-electron transfer and high-valent iron-oxo species from the O-atom transfer compete to be the reactive intermediates in the Fenton and related reactions. In the confined space…
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Keywords:
oxygen mediated;
fenton like;
singlet oxygen;
iron ... See more keywords