Oxygen-to-Oxygen Silyl Migration of α-Siloxy Sulfoxides and Oxidation-Triggered Allicin Formation.
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DOI: 10.1021/acs.orglett.1c01149
Abstract: Oxidation of α-siloxy thioethers leads to the formation of the corresponding sulfoxides as unstable intermediates, which undergo an intramolecular oxygen-to-oxygen silyl migration to break the C-S linkage. This process produces silyl protected sulfenic acids and… read more here.
Keywords: oxygen; oxygen silyl; oxidation; oxygen oxygen ... See more keywords