Chemoselective Decarboxylative Oxygenation of Carboxylic Acids To Access Ketones, Aldehydes, and Peroxides.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00649
Abstract: Reported here is a photocatalytic strategy for the chemoselective decarboxylative oxygenation of carboxylic acids using Ce(III) catalysts and O2 as the oxidant. By simply changing the base employed, we demonstrate that the selectivity of the… read more here.
Keywords: ketones aldehydes; oxygenation carboxylic; chemoselective decarboxylative; aldehydes peroxides ... See more keywords
Copper(II)-photocatalyzed decarboxylative oxygenation of carboxylic acids.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00570k
Abstract: Showcasing the concept of light-induced homolysis for the generation of radicals, the CuII-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two CuII-carboxylate complexes with different coordination geometries were… read more here.
Keywords: oxygenation carboxylic; carboxylic acids; photocatalyzed decarboxylative; copper photocatalyzed ... See more keywords