Kinetics of Reactions of Dirhodium and Diruthenium Paddlewheel Tetraacetate Complexes with Nucleophilic Protein Sites: Computational Insights.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02516
Abstract: Recently, dirhodium and diruthenium paddlewheel complexes have drawn attention as perspective anticancer drugs. In this study, the kinetics of reaction of typical paddlewheel scaffolds Rh2(μ-O2CCH3)4(H2O)2, Ru2(μ-O2CCH3)4(H2O)Cl, and [Ru2(μ-O2CCH3)4(HO)Cl]- with protein nucleophiles were investigated by means… read more here.
Keywords: substitution; diruthenium paddlewheel; paddlewheel; dirhodium diruthenium ... See more keywords
M24+ paddlewheel clusters as junction points in single-chain nanoparticles
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c8py01486h
Abstract: A straightforward approach to incorporate copper and molybdenum dimetallic clusters into well-defined single-chain nanoparticles, featuring unique paddlewheel structures as junction points, is introduced. read more here.
Keywords: junction points; single chain; paddlewheel; chain nanoparticles ... See more keywords
A dimolybdenum paddlewheel as a building block for heteromultimetallic structures.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04167b
Abstract: Diphenylphosphine functionalized propionic acid was applied for the synthesis of heteromultimetallic dimolybdenum(ii) complexes. The ligand features both carboxylic acid and phosphine functionalities, allowing the selective synthesis of a tetracarboxylate bridged Mo2(ii)-paddlewheel structure in a first… read more here.
Keywords: building block; heteromultimetallic structures; dimolybdenum paddlewheel; dimolybdenum complexes ... See more keywords
Effect of Fluorinated Ligand on Structural, Electronic and DNA-binding Properties of Copper Paddlewheel Complex: Synthesis, Structure and Properties.
Sign Up to like & getrecommendations! Published in 2018 at "Acta chimica Slovenica"
DOI: 10.17344/acsi.2017.3702
Abstract: This paper presents synthesis, structural description and properties of a binuclear paddlewheel copper(II) carboxylate complex with formula [(py)Cu(μ-L)4Cu(py)], where py = pyridine and L = 4-fluorophenylacetate. Structural characteristics, electronic absorption and DNA-binding properties of the… read more here.
Keywords: dna; dna binding; paddlewheel; effect ... See more keywords