Hammett-law Correlation in the Electron-donation Ability of trans-Heteroleptic Benzoate-bridged Paddlewheel-type Diruthenium(II,II) Complexes
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DOI: 10.1246/cl.180155
Abstract: A series of trans-heteroleptic paddlewheel-type diruthenium(II,II) complexes [Ru2(2,6-(CF3)2PhCO2)2(p-RPhCO2)2(THF)2] was synthesized by substituting para-R-substituted benzoate ligands (p-RPhCO2−, R = CF3, Cl, F, H, Ph, Me, MeO, OH) in [Ru2(p-RPhCO2)4(THF)2] with 2,6-bis(trifluoromethyl)benzoate (2,6-(CF3)2PhCO2−). The redox potential (E1/2)… read more here.
Keywords: diruthenium complexes; trans heteroleptic; paddlewheel type; type diruthenium ... See more keywords
6-Bromo-2-hydroxypyridinate-bridged Paddlewheel-Type Dirhodium Complex Isomers: Synthesis, Crystal Structures, Electrochemical Properties, and Structure-Dependent Absorption Properties
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DOI: 10.3390/inorganics12030070
Abstract: Two new paddlewheel-type dirhodium (Rh2) complex isomers, formulated as trans-2,2- and 3,1-forms of [Rh2(bhp)4] (bhp = 6-bromo-2-hydroxypyridinate), were obtained by the reaction of 6-bromo-2-hydroxypyridine with [Rh2(O2CCH3)4(H2O)2] and characterized by NMR, ESI-MS, and elemental analyses. Single… read more here.
Keywords: complex isomers; type dirhodium; structure; paddlewheel type ... See more keywords