A Tautomeric λ3/λ5-Phosphane Pair and Its Ambiphilic Reactivity.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00076
Abstract: The central phosphorus atom of a novel hydroxyl-functionalized triarylphosphane was shown to reversibly insert into one of the molecule's O-H bonds, which forms the basis for a tautomeric λ3/λ5-phosphane equilibrium. For the first time, this… read more here.
Keywords: tautomeric phosphane; equilibrium; reactivity; pair ambiphilic ... See more keywords
Access to a pair of ambiphilic phosphine-borane regioisomers by rhodium-catalyzed hydroboration.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01467a
Abstract: Lewis basic substrates, such as vinylphosphines and enamines, can be problematic for transition-metal catalysed hydrofunctionalization reactions due to their propensity to ligate and deactivate transition-metal catalysts as well as form direct Lewis adducts with reaction… read more here.
Keywords: access pair; phosphine; rhodium catalyzed; pair ambiphilic ... See more keywords