Second-Harmonic Generation and Photoluminescence Properties of Sn(II)- and Bi(III)-Based Lone Pair Cation-Pyridine Dicarboxylate Coordination Compounds.
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DOI: 10.1021/acs.inorgchem.0c01358
Abstract: Lone pair cation-based novel coordination compounds Sn[(pdc)(H2O)] (Sn-I) and (H2bpy)[Bi(pdc)2(Hpdc)]ยท5H2O (Bi-I) (pdc = pyridine-2,6-dicarboxylate; bpy = 4,4'-bipyridine) were synthesized through mild hydrothermal reactions. While Sn-I crystallizing in the polar space group, Pca21, exhibits a helical… read more here.
Keywords: coordination compounds; coordination; lone pair; second harmonic ... See more keywords