Frustrated Lewis Pair Chelation and Reactivity of Complexed Parent Iminoborane and Aminoborane.
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DOI: 10.1021/acs.inorgchem.2c02535
Abstract: An intramolecular phosphine-borane frustrated Lewis pair (FLP) chelate, iPr2P(C6H4)BCy2 or PB (Cy = cyclohexyl), was used to coordinate aminoborane (H2BNH2) and iminoborane (HBNH) units via donor-acceptor stabilization. Attempts to induce dehydrogenation from these B-N adducts… read more here.
Keywords: iminoborane; aminoborane; lewis pair; frustrated lewis ... See more keywords