Lewis Pair-Mediated Surface-Initiated Polymerization
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.7b00903
Abstract: We present the first example of surface-initiated polymerization mediated by Lewis pairs for the synthesis of polymer brushes on planar substrates. The method enables the rapid grafting polymerization from the self-assembled monolayer or surface-attached macroinitiators,… read more here.
Keywords: polymerization; lewis pair; surface; initiated polymerization ... See more keywords
Facile synthesis of cylindrical molecular brushes via Lewis pair-mediated polymerization
Sign Up to like & getrecommendations! Published in 2018 at "Polymer Chemistry"
DOI: 10.1039/c8py01257a
Abstract: We demonstrate the first application of Lewis pair-mediated polymerization (LPP) in the efficient synthesis of cylindrical molecular brushes bearing poly(methyl methacrylate) and polylactone side chains. Poly(N-heterocyclic olefin) (poly(NHO)) as a macroinitiator precursor was firstly prepared… read more here.
Keywords: molecular brushes; polymerization; lewis pair; pair mediated ... See more keywords