Lewis Pair Polymerization of Renewable Indenone to Erythro-Ditactic High-Tg Polymers with an Upcycling Avenue
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02285
Abstract: Preparation and storage of biorenewable, monomeric indenone, much less the polymerization to a well-defined, high-molecular-weight polymer, is challenging because of antiaromaticity-driven radical autopolymerization. Herein, we report the successful preparation and subsequent Lewis pair polymerization (LPP)… read more here.
Keywords: polymerization renewable; polymerization; lewis pair; renewable indenone ... See more keywords
Compounded Interplay of Kinetic and Thermodynamic Control over Comonomer Sequences by Lewis Pair Polymerization.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10568
Abstract: The design of facile synthetic routes to well-defined block copolymers (BCPs) from direct polymerization of one-pot comonomer mixtures, rather than traditional sequential additions, is both fundamentally and technologically important. Such synthetic methodologies often leverage relative… read more here.
Keywords: comonomer; lewis pair; pair polymerization; control comonomer ... See more keywords