Lewis Pair Polymerization of Renewable Indenone to Erythro-Ditactic High-Tg Polymers with an Upcycling Avenue
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02285
Abstract: Preparation and storage of biorenewable, monomeric indenone, much less the polymerization to a well-defined, high-molecular-weight polymer, is challenging because of antiaromaticity-driven radical autopolymerization. Herein, we report the successful preparation and subsequent Lewis pair polymerization (LPP)… read more here.
Keywords: polymerization renewable; polymerization; lewis pair; renewable indenone ... See more keywords
Compounded Interplay of Kinetic and Thermodynamic Control over Comonomer Sequences by Lewis Pair Polymerization.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10568
Abstract: The design of facile synthetic routes to well-defined block copolymers (BCPs) from direct polymerization of one-pot comonomer mixtures, rather than traditional sequential additions, is both fundamentally and technologically important. Such synthetic methodologies often leverage relative… read more here.
Keywords: comonomer; lewis pair; pair polymerization; control comonomer ... See more keywords
Entropy-Regulated Selective Synthesis of Cyclic Polymers and Polycatenanes by Lewis Pair Polymerization.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c07933
Abstract: While cyclic polymers offer a suite of unique material properties relative to their linear counterparts, their precision synthesis remains challenging and often relies on highly dilute reaction conditions to promote topological selectivity. Here, we unravel… read more here.
Keywords: pair polymerization; lewis pair; synthesis; cyclic polymers ... See more keywords