Articles with "paired electrolysis" as a keyword



One-step recovery of valuable metals from spent Lithium-ion batteries and synthesis of persulfate through paired electrolysis

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Published in 2021 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2021.129908

Abstract: Abstract The application of electrochemical methods on the recycling of valuable metals from spent lithium-ion batteries, and the removing of pollutant from wastewater by persulfate have attracted widespread attention in recent years. However, high energy… read more here.

Keywords: persulfate; valuable metals; spent lithium; paired electrolysis ... See more keywords

Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c01897

Abstract: A decarboxylative cyanation of amino acids under paired electrochemical reaction conditions has been developed. 4-CN-pyridine was found to be a new and effective cyanation reagent under catalyst-free conditions. Mechanistic studies support a nucleophilic reaction pathway,… read more here.

Keywords: cyanation pyridine; cyanation; paired electrolysis; decarboxylative cyanation ... See more keywords

Dehydroxylative Arylation of Alcohols via Paired Electrolysis.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c03136

Abstract: Nonactivated alcohols along with arene compounds are used in electrochemical dehydroxylative arylation for constructing C(sp3)-C(sp2) bonds. The PIII reagent undergoes single-electron anodic oxidation to form its radical cation, which reacts with the alcohol to produce… read more here.

Keywords: via paired; alcohols via; dehydroxylative arylation; paired electrolysis ... See more keywords

Merging Paired Electrolysis and Copper Catalysis Enables Electrochemical Arylation of Aziridine for the Synthesis of 1,2-Amino Tertiary Alcohols.

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Published in 2025 at "Organic letters"

DOI: 10.1021/acs.orglett.5c01417

Abstract: 1,2-Amino alcohols are omnipresent in bioactive molecules. Conventional approaches to this motif require multistep reactions. Herein, we develop an electrochemical strategy for copper-catalyzed convergent paired electrolysis. By selectively cleaving the C-N bond of 2-aryl-1-tosylaziridines with… read more here.

Keywords: copper; paired electrolysis; amino; merging paired ... See more keywords

Paired electrolysis enabled annulation for the quinolyl-modification of bioactive molecules

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d1sc06757e

Abstract: A paired electrolysis enabled cascade annulation that enables the efficient synthesis of highly functionalized quinoline-substituted bioactive molecules from readily available starting materials is reported. Using this methodology, two goals, namely, the direct synthesis of quinolines… read more here.

Keywords: enabled annulation; annulation; paired electrolysis; electrolysis enabled ... See more keywords

Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc02745c

Abstract: A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been… read more here.

Keywords: electron deficient; convergent paired; deficient alkenes; paired electrolysis ... See more keywords

Paired electrolysis enables decarboxylative coupling of alkenyl acids with diazo compounds

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Published in 2023 at "Organic Chemistry Frontiers"

DOI: 10.1039/d3qo00370a

Abstract: Herein, we have reported an efficient and green paired electrolysis strategy for decarboxylative coupling of alkenyl acids with diazo compounds, providing a broad range of β,γ-alkenyl esters and amides. read more here.

Keywords: alkenyl acids; diazo compounds; paired electrolysis; decarboxylative coupling ... See more keywords

Efficient co-production of ammonia and formic acid from nitrate and polyester via paired electrolysis.

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Published in 2025 at "Materials horizons"

DOI: 10.1039/d5mh00130g

Abstract: Paired electrolysis, which integrates a productive cathodic reaction, such as the nitrate reduction reaction (NO3-RR) with selective oxidation at the anode, offers an intriguing way to maximize both atomic and energy efficiency. However, in a… read more here.

Keywords: via paired; formic acid; electrolysis; paired electrolysis ... See more keywords

Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates

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Published in 2023 at "Molecules"

DOI: 10.3390/molecules28031397

Abstract: The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free, energy-saving… read more here.

Keywords: diselenides kscn; cyanation diaryl; enabled cyanation; paired electrolysis ... See more keywords