One-step recovery of valuable metals from spent Lithium-ion batteries and synthesis of persulfate through paired electrolysis
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.129908
Abstract: Abstract The application of electrochemical methods on the recycling of valuable metals from spent lithium-ion batteries, and the removing of pollutant from wastewater by persulfate have attracted widespread attention in recent years. However, high energy… read more here.
Keywords: persulfate; valuable metals; spent lithium; paired electrolysis ... See more keywords
Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01897
Abstract: A decarboxylative cyanation of amino acids under paired electrochemical reaction conditions has been developed. 4-CN-pyridine was found to be a new and effective cyanation reagent under catalyst-free conditions. Mechanistic studies support a nucleophilic reaction pathway,… read more here.
Keywords: cyanation pyridine; cyanation; paired electrolysis; decarboxylative cyanation ... See more keywords
Dehydroxylative Arylation of Alcohols via Paired Electrolysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03136
Abstract: Nonactivated alcohols along with arene compounds are used in electrochemical dehydroxylative arylation for constructing C(sp3)-C(sp2) bonds. The PIII reagent undergoes single-electron anodic oxidation to form its radical cation, which reacts with the alcohol to produce… read more here.
Keywords: via paired; alcohols via; dehydroxylative arylation; paired electrolysis ... See more keywords
Paired electrolysis enabled annulation for the quinolyl-modification of bioactive molecules
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06757e
Abstract: A paired electrolysis enabled cascade annulation that enables the efficient synthesis of highly functionalized quinoline-substituted bioactive molecules from readily available starting materials is reported. Using this methodology, two goals, namely, the direct synthesis of quinolines… read more here.
Keywords: enabled annulation; annulation; paired electrolysis; electrolysis enabled ... See more keywords
Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02745c
Abstract: A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been… read more here.
Keywords: electron deficient; convergent paired; deficient alkenes; paired electrolysis ... See more keywords
Paired electrolysis enables decarboxylative coupling of alkenyl acids with diazo compounds
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00370a
Abstract: Herein, we have reported an efficient and green paired electrolysis strategy for decarboxylative coupling of alkenyl acids with diazo compounds, providing a broad range of β,γ-alkenyl esters and amides. read more here.
Keywords: alkenyl acids; diazo compounds; paired electrolysis; decarboxylative coupling ... See more keywords
Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031397
Abstract: The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free, energy-saving… read more here.
Keywords: diselenides kscn; cyanation diaryl; enabled cyanation; paired electrolysis ... See more keywords