Anion-Responsive Boron-Spiro-Centered π-Electronic Systems That Form Ion-Pairing Assemblies.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00073
Abstract: A variety of naphthalenediolates were orthogonally introduced to the boron unit of dipyrrolyldiketone boron complexes, exhibiting electronic properties that depended on the substituting positions of the naphthyl moieties. Combining the anion complexes with countercations resulted… read more here.
Keywords: ion pairing; pairing assemblies; responsive boron; boron ... See more keywords
Ion-pairing assemblies of π-extended anion-responsive organoplatinum complexes
Sign Up to like & getrecommendations! Published in 2024 at "Science and Technology of Advanced Materials"
DOI: 10.1080/14686996.2024.2313958
Abstract: ABSTRACT PtII complexes of π-extended dipyrrolyldiketones were synthesized as anion-responsive π-electronic molecules. The dipyrrolyldiketone PtII complexes exhibited red-shifted absorption and photoluminescence properties. In the solid state, [1 + 1]-type anion complexes formed charge-by-charge ion-pairing assemblies when combined… read more here.
Keywords: anion; ion pairing; anion responsive; pairing assemblies ... See more keywords