Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly.
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DOI: 10.1039/c7dt01635b
Abstract: The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species as the building unit of… read more here.
Keywords: building unit; unit ion; pairing assembly; ion pairing ... See more keywords