Enantioselective C,P-Palladacycle-Catalyzed Arylation of Imines
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DOI: 10.1021/acsomega.0c01124
Abstract: Chiral diarylmethylamines are of great interest because of their prevalence in biological and pharmaceutical sciences. Herein, we report a C,P-palladacycle-catalyzed enantioselective synthesis of chiral diarylmethylamines via asymmetric arylation of N-protected imines with arylboronic acids. The… read more here.
Keywords: arylation imines; enantioselective palladacycle; arylation; palladacycle catalyzed ... See more keywords
Versatile halogenation via a CNHC^Csp3 palladacycle intermediate.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00113j
Abstract: Stable cyclopalladated complexes containing an (sp3)C-Pd bond were synthesized via α-CH2 deprotonation and palladation of N-alkyl groups of carbene ligands bearing electron-withdrawing substituents. The strong electron donating strengths of the resulting CNHC^Csp3 chelators were experimentally… read more here.
Keywords: cnhc csp3; palladacycle; halogenation via; versatile halogenation ... See more keywords