Controlled immobilization of a palladium complex/laccase hybrid into a macrocellular siliceous host.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300156
Abstract: This study investigates the site-directed immobilization of a hybrid catalyst bearing a biquinoline-based-Pd(II) complex (1) and a robust laccase within cavities of a silica foam to favor veratryl alcohol oxidation. We performed the grafting of… read more here.
Keywords: immobilization; immobilization palladium; complex laccase; palladium complex ... See more keywords
Fabrication of Nanoreactors Based on End-Functionalized Polymethacrylate and Their Catalysis Application
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-020-01599-2
Abstract: Abstract Polymer-based nanoreactor, which can be achieved by self-assembling of amphiphilic polymers in water, has attracted more and more attention in recent years. In this study, a kind of Pd-nanoreactor was fabricated by self-assembling of… read more here.
Keywords: palladium complex; end functionalized; based end; fabrication nanoreactors ... See more keywords
Phosphine/N-heterocyclic carbene palladium complex for Suzuki-Miyaura cross-coupling reactions: The role of water on activity
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.04.021
Abstract: Abstract A new bidentate ferrocenyl phosphine/N-heterocyclic carbene (NHC) palladium complex rac-6, bearing a functionalized pendant arm for further grafting on a solid surface, has been synthesized in good yields and fully characterized. The molecular structure… read more here.
Keywords: water; activity; heterocyclic carbene; suzuki miyaura ... See more keywords
Amidoxime modified PAN supported palladium complex: A greener and efficient heterogeneous catalyst for heck reaction
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119305
Abstract: Abstract Development of a facile and greener approach for Heck reaction using a modified PAN supported palladium catalyst is described. The preparation of the catalyst involves a simple process through amidoxime modification of nitrile group… read more here.
Keywords: palladium complex; supported palladium; reaction; heck ... See more keywords
Vibrational and Hirshfeld surface analyses, quantum chemical calculations, and molecular docking studies of coumarin derivative 3-(1-m-toluidinoethylidene)-chromane-2,4-dione and its corresponding palladium(II) complex
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.127935
Abstract: Abstract In this study, the analysis of vibrational spectra and electronic structure of 3-(1-m-toluidinoethylidene)-chromane-2,4-dione (L1) and its corresponding palladium (II) complex (C1) was employed to characterize the spectroscopic behavior and molecular structure of the investigated… read more here.
Keywords: toluidinoethylidene chromane; palladium complex; dione corresponding; corresponding palladium ... See more keywords
1,2,3-Triazolylidene palladium complex with triazole ligand: Synthesis, characterization and application in Suzuki–Miyaura coupling reaction in water
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2018.10.022
Abstract: Abstract Palladium complex containing 1,2,3-triazolylidene and a labile triazole moiety has been prepared and characterized. Simple azide alkyne click reaction using three fold excess of dibromoethane afforded 1-(2-bromoethyl)-4-phenyl-1H-1,2,3-triazole. The latter on dehydrobromination yields N-vinyl triazole… read more here.
Keywords: miyaura coupling; reaction; coupling reaction; suzuki miyaura ... See more keywords
Visible-light-mediated hydrodehalogenation and Br/D exchange of inactivated aryl and alkyl halides with a palladium complex
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00240e
Abstract: Photo-induced radical reductive dehalogenation of inactivated aryl/alkyl bromides and chlorides with a palladium complex is described. Reductive cyclization, dehalogenative deuteration, and radical addition process can be achieved smoothly. read more here.
Keywords: palladium complex; visible light; aryl alkyl; inactivated aryl ... See more keywords
Selective hydrogenation of acetylene to ethylene by alkali-metal palladium complex hydrides.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc07080d
Abstract: A series of alkali-metal palladium complex hydrides have been shown to be catalytically active and selective for partial hydrogenation of acetylene to ethylene. The complex hydrides differ in composition, structure, and catalytic function as compared… read more here.
Keywords: metal palladium; hydrogenation acetylene; acetylene ethylene; palladium complex ... See more keywords
Synthesis and characterization of thiophene-derived palladium(ii) complex immobilized on FSM-16 and its application in the novel synthesis of 7-(aryl)-7,12-dihydro-6H-indeno[1,2,4]triazolo[1,5-a]pyrimidine-6-one derivatives
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra06271b
Abstract: The present study aims at synthesizing a palladium complex with a thiophene-carboimine ligand, supported on FSM-16 as a mesoporous silica support. Firstly, the prepared FSM-16 was modified using 3-aminopropyl group. The imine bond was subsequently… read more here.
Keywords: indeno triazolo; triazolo pyrimidine; thiophene; synthesis ... See more keywords
A palladium complex of a macrocyclic selenium ligand: catalyst for the dehydroxymethylation of dihydroxy compounds.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00375b
Abstract: This report describes the synthesis of a seventeen-membered macrocyclic ring containing ligand (L1) by the reaction of 1,8-bis(2-(chloromethyl)phenoxy)octane with selenium powder. The trans-palladium dichloride complex (C1) of the macrocyclic selenium ligand was synthesized from its… read more here.
Keywords: dehydroxymethylation; catalyst; ligand; palladium complex ... See more keywords
Synthesis and electropolymerization of EDOT modified 1,3-bis(5-methyl-2-thiazolylimino)isoindolinato palladium(II) complex for electrochemical detection of hydrogen peroxide
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2017.1322695
Abstract: Abstract 1,3-Bis(5-methyl-2-thiazolylimino) isoindoline derivative (EDOT-BTI) containing an electropolymerizable group is prepared using the Linstead method. According to this two-step method phthalonitrile derivative EDOT-Pht is converted to 1,3-diiminoisoindoline EDOT-DII first then EDOT-DII is reacted with 2-amino-5-methylthiazole… read more here.
Keywords: palladium complex; bis methyl; methyl thiazolylimino; palladium ... See more keywords