Cationic Palladium(II) Complexes for Catalytic Wacker-Type Oxidation of Styrenes to Ketones using O2 as the Sole Oxidant
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700931
Abstract: A series of new palladium(II) complexes were prepared and studied for their ability to catalyze the Wacker-type oxidation of styrenes to their corresponding acetophenones using oxygen as the sole oxidant. Catalysts are active at room… read more here.
Keywords: sole oxidant; palladium complexes; wacker type; oxidation styrenes ... See more keywords
Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.02.004
Abstract: Abstract A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2 as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were… read more here.
Keywords: palladium complexes; acetylacetonate palladium; cationic acetylacetonate; hydroamination vinylarenes ... See more keywords
Palladium(II) complexes with N-alkyliminodiacetic acid derivatives: preparation, structural and spectroscopic studies
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.03.010
Abstract: Abstract The reactions of N-alkyl derivatives of iminodiacetic acid, RN(CH2COOH)2 (i-PridaH2 and t-BuidaH2; i-Pr = isopropyl, t-Bu = tert-butyl) with sodium tetrachloropalladate(II) in aqueous solutions were investigated. Four new palladium(II) complexes {[Na[PdCl(i-Prida)](H2O)2]·1/2H2O}n (1), [Na[PdCl(t-Buida)](H2O)2]n (2), [Pd(i-PridaH)2]·2H2O (3) and [Pd(t-BuidaH)2]… read more here.
Keywords: palladium complexes; buida; spectroscopy; acid ... See more keywords
Palladium complexes bearing pyridylthioether ligands. Synthesis and application as efficient phosphine-free catalysts in Suzuki-Miyaura couplings
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.12.029
Abstract: Abstract Pyridylthiother-ligated Pd(II) complexes have been synthesized and efficiently applied in Suzuki-Miyaura couplings using microwave irradiation in DMF and water. The pyridylthioether NS (NS1 and NS2) and pyridyldithiother (SNS) ligands and their corresponding palladium complexes… read more here.
Keywords: palladium complexes; miyaura couplings; suzuki miyaura; sns ... See more keywords
Synthesis, spectroscopic characterization, biological activity, DFT and molecular docking study of novel 4-hydroxycoumarine derivatives and corresponding palladium(II) complexes
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119465
Abstract: Abstract In the present manuscript, palladium(II) complexes (C1, C2) with newly synthesized coumarine ligands 3-(1-((3-chlorophenyl)amino)ethylidene)-chroman-2,4-dione (L1) and 3-(1-((4-chlorophenyl)amino)ethylidene)-chroman-2,4-dione (L2) were prepared and structurally characterized by spectroscopic techniques (FT-IR, 1H NMR, 13C NMR) in combination with… read more here.
Keywords: palladium complexes; synthesis spectroscopic; spectroscopic characterization; activity ... See more keywords
New Palladium(II) complexes with ONO chelated hydrazone ligand: Synthesis, characterization, DNA/BSA interaction, antioxidant and cytotoxicity
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119868
Abstract: Abstract There is a continuous finding of suitable metal complexes for biomedical and biological applications since the discovery of cisplatin. Two biologically active complexes (2 and 3) are synthesized by using 2-chloro-benzoic acid (3,5-dichloro-2-hydroxy-benzylidene)-hydrazide (1)… read more here.
Keywords: palladium complexes; dna; complexes ono; interaction ... See more keywords
Synthesis, characterization, HSA/DNA binding, cytotoxicity study, and antimicrobial activity of new palladium(II) complexes with some esters of (S,S)-propylenediamine-N,N'-di-2-(3-methyl)butanoic acid
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DOI: 10.1016/j.ica.2021.120601
Abstract: Abstract In this paper, we presented synthesis, characterization, HSA/DNA binding evaluation, in vitro cytotoxic activity and in vitro antimicrobial activity of three new ligands of general formula. R2-S,S-pddmb (L1-L3) and their corresponding palladium(II) complexes of… read more here.
Keywords: palladium complexes; hsa dna; activity; spectroscopy ... See more keywords
Novel copper(II) and palladium(II) complexes with 4-aroyl-5-pyrazolone ligands: Synthesis and characterization
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.05.026
Abstract: Abstract Novel bidentate 4-aroyl-5-pyrazolone ligands were synthesized and reacted with copper(II) and palladium(II) salts in 1:2 (metal:ligand) equimolar ratio leading to the formation of eight new coordination compounds. All synthesized compounds were characterized by FTIR,… read more here.
Keywords: copper; pyrazolone; palladium complexes; aroyl pyrazolone ... See more keywords
Palladium(II) complexes containing sterically bulky O, N donor ligands: Synthesis, characterization and catalytic activity in the Suzuki-Miyaura and Sonogashira coupling reactions
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.121080
Abstract: Abstract A new class of palladium(II)1-(arylazo)naphtholate complexes of the type [Pd(L1-4)2] containing sterically bulky O, N donor functionalized arylazo ligands has been synthesized. These palladium(II) complexes were characterized by elemental analysis and spectral (FT-IR, UV–Vis,… read more here.
Keywords: containing sterically; palladium complexes; sterically bulky; bulky donor ... See more keywords
Palladium(II) Complexes Bearing a Mixed Set of aNHC/Py/PR3/I2 Ligands: Applications in α-Arylation of Amide and Suzuki-Miyaura Coupling Reactions
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DOI: 10.1016/j.jorganchem.2021.121925
Abstract: ABSTRACT Complexes possessing abnormal or mesoionic carbene (aNHC or MIC) ligands are finding widespread applicability in organometallic chemistry owing to their various catalytic applications. Palladium(II) complexes bearing a mixed aNHC/Py/PR3/I2 (R = Ph, Cy) donor set are… read more here.
Keywords: anhc pr3; bearing mixed; complexes bearing; suzuki miyaura ... See more keywords
Recent advances in polymer supported palladium complexes as (nano)catalysts for Sonogashira coupling reaction
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DOI: 10.1016/j.mcat.2019.110645
Abstract: Abstract Palladium (Pd) complexes supported on the polymers have been widely used in various organic syntheses endeavors because of their thermal stability, high catalytic activities and recyclability. This article provides contemporary advancements in the deployment… read more here.
Keywords: palladium complexes; sonogashira coupling; advances polymer; recent advances ... See more keywords