PC-Phos Enabled Catalytic Palladium-heteroallyl Asymmetric Cycloaddition.
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DOI: 10.1021/jacs.2c09799
Abstract: Asymmetric cycloaddition reactions are the most powerful tool to the expeditious construction of enantioenriched cyclic motifs in organic chemistry. In sharp contrast to well-developed cycloaddition reactions via the palladium-trimethylenemethane (Pd-TMM) intermediate, hetero (3 + 2)… read more here.
Keywords: palladium heteroallyl; asymmetric cycloaddition; phos; cycloaddition ... See more keywords