Spectral, crystallographic, theoretical and antibacterial studies of palladium(II)/platinum(II) complexes with unsymmetric diphosphine ylides
Sign Up to like & getrecommendations! Published in 2018 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.4658
Abstract: The reaction of alpha-keto-stabilized diphosphine ylides [Ph2P(CH2)(n)PPh2C(H)C(O)C6H4-p-CN] (n = 1 (Y-1); n = 2 (Y-2)) with dibromo(1,5-cyclooctadiene) palladium(II)/platinum(II) complexes, [Pd/PtBr2(cod)], in equimolar ratio gave the new cyclometalated Pd(II) and Pt(II) complexes [Br2Pd(kappa(2)-Y-1)] (1), [Br2Pt(kappa(2)-Y-1)] (2),… read more here.
Keywords: palladium platinum; spectral crystallographic; diphosphine ylides; platinum complexes ... See more keywords
Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700810
Abstract: Perfluorination of one η5-C5H5 ring in the MC10H10 system (M = Ni, Pd, Pt) to give an MC10H5F5 system greatly destabilizes structures containing a perfluorinated pentahapto η5-C5F5 ring. As a result, the metallapentafluorobenzene structures (η5-C5H5)(MC5F5)… read more here.
Keywords: perfluorination; energy; palladium platinum; nickel palladium ... See more keywords
Synthesis and crystal structures of phenylalanine ester-introduced palladium(II) and platinum(II) complexes and their cytotoxicities
Sign Up to like & getrecommendations! Published in 2018 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-018-3623-6
Abstract: Abstract Phenylalanine ester-introduced palladium(II) and platinum(II) complexes were synthesized. Taking advantage of the formation of Schiff bases by amino acids as an intermediate, the pyridylimine moiety coordinated to a metal center. Single crystals of each… read more here.
Keywords: ester introduced; palladium platinum; introduced palladium; phenylalanine ester ... See more keywords
The role of electrolytically deposited palladium and platinum metal nanoparticles dispersed onto poly(1,8-diaminonaphthalene) for enhanced glucose electrooxidation in biofuel cells
Sign Up to like & getrecommendations! Published in 2020 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2020.136781
Abstract: Abstract Glucose biofuel cells are one of the promising power supplies with a competent long-term stability and power density. In this respect, catalysts of palladium (Pd) and platinum (Pt) metal nanoparticles film coated electrode were… read more here.
Keywords: electrooxidation; biofuel; metal nanoparticles; palladium platinum ... See more keywords
Oxygen crossover effect on palladium and platinum based electrocatalysts during formic acid oxidation studied by scanning electrochemical microscopy
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2016.12.049
Abstract: This work was financially supported by CNRS (projet ImaECell, Defi Instrumentation aux limites 2015), MINECO (projects CTQ2013-44083-P and CTQ2013-48280-C3-3-R) and Generalitat Valenciana (project PROMETEOII/2014/013). J. Solla-Gullon acknowledges financial support from VITC (Vicerrectorado de Investigacion y… read more here.
Keywords: effect palladium; crossover effect; platinum based; microscopy ... See more keywords
Palladium and platinum based solid and hollow nanoparticles: An ab-initio study of structural and electronic properties
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2018.01.020
Abstract: Abstract Nanoparticles composed of palladium and platinum are particularly interesting for catalytic purposes, for instance, selective hydrogenation and alcohol oxidation. The reactivity and selectivity of nanostructures are mostly based on the size and shape of… read more here.
Keywords: platinum; platinum based; palladium platinum; hollow nanoparticles ... See more keywords
DNA interaction and anticancer evaluation of new palladium(II), platinum(II) and silver(I) complexes based on (Δ)- and (Λ)-1,2–bis-(1H-benzimidazol-2-yl)-1,2-ethanediol enantiomers
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.020
Abstract: Abstract The synthesis of some new palladium(II), platinum(II) and silver(I) complexes based on (Δ)- and (Λ)-1,2–bis-(1H-benzimidazol-2-yl)-1,2-ethanediol (Δ-H2bie and Λ-H2bie) enantiomers in the absence and presence of the N,N-chelates 2,2′-bipyridyl and 9,10-phenanthroline, and triphenylphosphine is reported.… read more here.
Keywords: platinum silver; silver complexes; palladium platinum; complexes based ... See more keywords
New nickel, palladium and platinum complexes of hydantoin derivative: Synthesis, characterization, theoretical study and biological activity
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DOI: 10.1016/j.poly.2020.114478
Abstract: Abstract New Ni(II), Pd(II) and Pt(II) complexes of 5-methyl-5-(4-nitrophenyle)-hydantoin (L) were synthesized, characterized and their biological activities were evaluated. The resulting spectroscopic and theoretical data offered strong evidences for coordination of hydantoin based ligand from… read more here.
Keywords: theoretical study; palladium platinum; nickel palladium; activity ... See more keywords
iClick Reactions of Square-Planar Palladium(II) and Platinum(II) Azido Complexes with Electron-Poor Alkynes: Metal-Dependent Preference for N1 vs N2 Triazolate Coordination and Kinetic Studies with 1H and 19F NMR Spectroscopy.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01304
Abstract: Two square-planar palladium(II) and platinum(II) azido complexes [M(N3)(L)] with L = N-phenyl-2-[1-(2-pyridinyl)ethylidene]hydrazine carbothioamide reacted with four different electron-poor alkynes R-C≡C-R' with R = R' = COOCH3, COOEt, COOCH2CH2OCH3 or R = CF3, R' = COOEt… read more here.
Keywords: palladium platinum; nmr spectroscopy; square planar; planar palladium ... See more keywords
Experimental and computational tuning of metalla-N-heterocyclic carbenes at palladium(II) and platinum(II) centers.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00252c
Abstract: Palladium(II) and platinum(II) complexes featuring metalla-N-heterocyclic carbenes (7-12) were synthesised via metal-mediated coupling between equimolar cis-[MCl2(CNR)2] (R = 2,6-Me2C6H3 (Xyl), 2,4,6-Me3C6H3 (Mes)) and 2-aminopyridine or 2-aminopyrazine. Thiocyanate complexes 13-18 with two thiocyanate ligands were obtained… read more here.
Keywords: metalla heterocyclic; palladium platinum; heterocyclic carbenes;
Dry reforming of methane over palladium–platinum on carbon nanotube catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Communications"
DOI: 10.1080/00986445.2017.1423065
Abstract: ABSTRACT A dry reforming (DR) catalyst based on bimetallic Pd–Pt supported on carbon nanotubes is presented. The catalyst was prepared using a microwave-induced synthesis. It showed enhanced DR activity in the 773–923 K temperature range at… read more here.
Keywords: dry reforming; reforming methane; carbon; palladium platinum ... See more keywords