Synthesis and structural characterization of alkyne-functionalized N-heterocyclic carbene complexes of ruthenium, palladium and rhodium
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.034
Abstract: Abstract A series of novel ruthenium(II), palladium(II) and rhodium(I) complexes bearing N-heterocyclic carbene ligand functionalized by an alkyne-protected functional group ( C C SiMe3) were synthesized by transmetalation from the silver-NHC intermediate or by deprotonation… read more here.
Keywords: palladium rhodium; rhodium; ruthenium palladium; alkyne functionalized ... See more keywords
Stereodivergent Palladium- and Rhodium-Catalyzed Intramolecular Addition of Tosylureas to Allenes: Diastereoselective Synthesis of Tetrahydropyrimidinones.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c03482
Abstract: The intramolecular addition of tosylureas to allenes is highly syn-/anti-diastereoselective when employing a palladium or rhodium-based catalytic system and affords 1,3-cyclic ureas. Under palladium catalysis a range of thermodynamic anti-tetrahydropyrimidinones are accessible, while rhodium catalysis… read more here.
Keywords: rhodium; intramolecular addition; palladium rhodium; tosylureas allenes ... See more keywords
Synthesis of pyrrole-based PSiP pincer ligands and their palladium, rhodium, and platinum complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00948j
Abstract: The synthesis and coordination chemistry of a new class of silyl pincer ligand featuring pyrrole-based linkers is reported. The steric and electronic properties of these bis(phosphinopyrrole)methylsilane ligands were interrogated using their palladium, rhodium, and platinum… read more here.
Keywords: platinum complexes; pincer; palladium rhodium; rhodium platinum ... See more keywords