Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene
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DOI: 10.1021/acs.organomet.9b00295
Abstract: The reaction chemistry of metalla-aromatics is fundamentally interesting. In this work, we find that tetralithio spiroaromatic palladole and platinacycle complexes 1 undergo selective two-electron oxidation with 1,2-dibromoethane as a mild oxidant, affording their corresponding dilithio… read more here.
Keywords: dicupra annulene; palladole platinacycle; electron redox; reversible two ... See more keywords