Kinetic Studies Reveal that the Secondary Station Impacts the Rate of Motion of Cyclobis(Paraquat‐p‐Phenylene) in Out‐of‐Equilibrium [2]Rotaxanes
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DOI: 10.1002/cplu.202500154
Abstract: Control of movement in artificial molecular machines relies on the formation of out‐of‐equilibrium states that can subsequently interconvert to their ground states. However, a detailed description of molecular machines that are out of equilibrium is… read more here.
Keywords: station; cyclobis paraquat; paraquat phenylene; equilibrium ... See more keywords
Supramolecular Hydrogels with Tunable Swelling by Host Complexation with Cyclobis(paraquat-p-phenylene)
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DOI: 10.1021/acs.macromol.0c02535
Abstract: Controlling the swelling properties of hydrogels is of primary importance for many applications ranging from actuators and valves to tissue engineering and drug delivery. Herein, we report the use of cyclobis(paraquat-p-phenylene) (CBPQT4+,4X–) as a versatile… read more here.
Keywords: supramolecular hydrogels; cyclobis paraquat; complexation; paraquat phenylene ... See more keywords