Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response
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DOI: 10.1021/acs.chemmater.8b04428
Abstract: An effective approach, the partial aliovalent cation substitution (PACS), was successfully employed to develop nonlinear optical (NLO) material. Two novel rare earth carbonates, Y2(CO3)3·H2O (YC) and (NH4)2Ca2Y4(CO3)9·H2O (CYC), were synthesized, which feature the same honeycomb-like… read more here.
Keywords: co3 h2o; partial aliovalent; aliovalent cation; substitution ... See more keywords