Effect of the fluorination degree of partially fluorinated octyl-phosphocholine surfactants on their interfacial properties and interactions with purple membrane as a membrane protein model.
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry and physics of lipids"
DOI: 10.1016/j.chemphyslip.2020.104870
Abstract: Interfacial properties and membrane protein solubilization activity of a series of partially fluorinated octyl-phosphocholine (PC) surfactants were investigated from the viewpoint of the fluorination degree of the hydrophobic chain. The critical micelle concentration (CMC), surface… read more here.
Keywords: partially fluorinated; interfacial properties; fluorination; fluorinated octyl ... See more keywords
A novel synthesis approach to partially fluorinated sulfonimide based poly (arylene ether sulfone) s for proton exchange membrane
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.01.178
Abstract: Abstract Innovation of novel low cost proton conductive materials with super acidity has been the ever-increasing thirst for PEMFCs. Sulfonimide groups have the strongest gas-phase super-acidity with excellent thermal and chemical stability. Therefore, a series… read more here.
Keywords: fluorinated sulfonimide; proton; arylene ether; poly arylene ... See more keywords
Reaction of perfluorinated and partially fluorinated olefins with fluorinated thioketones. Efficient synthesis of perfluorinated 1,3-dithioles
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2021.109775
Abstract: Abstract While the reaction of F-butene-2 and F-pentene-2 with sulfur, CsF catalyst and 2,2,4,4-tetrakis(trifluoromethyl)-dithietane-1,3 at ambient temperature produced an equimolar mixture of the corresponding perfluorinated 1,3-dithiole and branched perfluorinated polysulfides, it was discovered that the… read more here.
Keywords: reaction perfluorinated; perfluorinated partially; reaction; partially fluorinated ... See more keywords
Influence of hydrocarbon moieties of partially fluorinated N-benzoyl thiourea compounds on their gelation properties. A detailed rheological study of complex viscoelastic behavior of decanol/N-benzoyl thiourea mixtures
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.01.162
Abstract: Abstract The gelation ability of a series of partially fluorinated N -benzoyl- N′ -aryl thiourea derivatives (BTUs) newly designed and synthesized was examined in six different alcohols (ethanol, 1-propanol, 2-propanol, 1-butanol, 1-octanol and 1-decanol). After… read more here.
Keywords: partially fluorinated; gelation; fluorinated benzoyl; microscopy ... See more keywords
Partially fluorinated Scorpionate [HB(3-(CF3),5-(Ph)Pz)3]− as a supporting ligand for silver(I)-benzene, -carbonyl, and -PPh3 complexes
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2016.09.014
Abstract: Abstract The benzene, CO, and PPh3 adducts [HB(3-(CF3),5-(Ph)Pz)3]AgL (L = C6H6, CO, or PPh3) have been synthesized by a metathesis process using [HB(3-(CF3),5-(Ph)Pz)3]Na(THF), CF3SO3Ag, and the corresponding co-ligands. These silver(I) adducts have been characterized by NMR spectroscopy,… read more here.
Keywords: partially fluorinated; pph3; fluorinated scorpionate; cf3 ... See more keywords
Membrane properties of trisulfonated hydrophilic and partially fluorinated hydrophobic multiblock copolymer
Sign Up to like & getrecommendations! Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.123810
Abstract: Abstract A multiblock copolymer with increased charge density in the hydrophilic phase was synthesized by utilizing a trisulfonated poly(arylene ether sulfone) backbone (SHQS100). To achieve a balance of membrane properties a partially fluorinated poly(arylene ether… read more here.
Keywords: partially fluorinated; fluorinated hydrophobic; phase; multiblock copolymer ... See more keywords
Fabricating a Partially Fluorinated Hybrid Cation-Exchange Membrane for Long Durable Performance of Vanadium Redox Flow Batteries.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c16720
Abstract: The long-term durability of vanadium redox flow batteries (VRFBs) depends on the stability and performance of the membrane separator. We have architected a hybrid membrane by uniform dispersion of MIL-101(Cr) (Cr-MOF) in a partially fluorinated… read more here.
Keywords: redox flow; mof; vanadium redox; membrane ... See more keywords
Synergistic Effect of Partially Fluorinated Ether and Fluoroethylene Carbonate for High-Voltage Lithium-Ion Batteries with Rapid Chargeability and Dischargeability.
Sign Up to like & getrecommendations! Published in 2017 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.7b12352
Abstract: The roles of a partially fluorinated ether (PFE) based on a mixture of 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane and 2-(difluoro(methoxy)methyl)-1,1,1,2,3,3,3-heptafluoropropane on the oxidative durability of an electrolyte under high-voltage conditions, the rate capability of the graphite and 5 V-class… read more here.
Keywords: high voltage; voltage; partially fluorinated; fluorinated ether ... See more keywords
Langmuir–Blodgett Monolayers of Partially Fluorinated Ionic Liquids as Two-Dimensional, More Sustainable Functional Materials and Coatings
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.9b01496
Abstract: The structure of cations and anions in ionic liquids is precisely selected to tune their properties for applications in catalysis, electrochemistry, or development of sensors. Substitution of a hyd... read more here.
Keywords: monolayers partially; fluorinated ionic; langmuir blodgett; partially fluorinated ... See more keywords
Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo2O8F.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c06061
Abstract: Strong second-harmonic generation (SHG) and a wide band gap are two crucial but often conflicting parameters that must be optimized for practical nonlinear optical (NLO) materials. We report herein the first d0-transition-metal (TM) tellurite with… read more here.
Keywords: partially fluorinated; band gap; harmonic generation; band ... See more keywords
Organometallic chemistry using partially fluorinated benzenes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc09575e
Abstract: Fluorobenzenes, in particular fluorobenzene (FB) and 1,2-difluorobenzene (1,2-DiFB), are increasingly becoming recognised as versatile solvents for conducting organometallic chemistry and transition-metal-based catalysis. The presence of fluorine substituents reduces the ability to donate π-electron density from… read more here.
Keywords: partially fluorinated; fluorinated benzenes; chemistry; using partially ... See more keywords