Assessing the 4f Orbital Participation in the Ln-C Bonds of [Li(THF)4][Ln(C6Cl5)4] (Ln = La, Ce).
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DOI: 10.1021/acs.inorgchem.2c02304
Abstract: The reaction of [Ln(NO3)3(THF)4] (Ln = La, Ce) with 4 equiv of LiC6Cl5 in Et2O resulted in the formation of the homoleptic lanthanide-aryl "ate" complexes [Li(THF)4][La(C6Cl5)4] ([Li][1]) and [Li(THF)4][Ce(C6Cl5)4] ([Li][2]). These complexes represent the first… read more here.
Keywords: assessing orbital; thf c6cl5; participation bonds; orbital participation ... See more keywords