Articles with "pcet" as a keyword



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Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer.

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Published in 2022 at "Chemical reviews"

DOI: 10.1021/acs.chemrev.1c00929

Abstract: Proton-coupled electron transfer (PCET) plays an essential role in a wide range of electrocatalytic processes. A vast array of theoretical and computational methods have been developed to study electrochemical PCET. These methods can be used… read more here.

Keywords: coupled electron; proton; electron transfer; proton coupled ... See more keywords
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Luminescent Iridium Complexes with a Sulfurated Bipyridine Ligand: PCET Thermochemistry of the Disulfide Unit and Photophysical Properties.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01930

Abstract: Molecular systems combining light harvesting and charge storage are receiving great attention in the context of, for example, artificial photosynthesis and solar fuel generation. As part of ongoing efforts to develop new concepts for photoinduced… read more here.

Keywords: bipyridine ligand; state; sulfurated bipyridine; ligand ... See more keywords

Enantioselective Addition of Remote Alkyl Radicals to Double Bonds by Photocatalytic Proton-Coupled Electron Transfer (PCET) Deconstruction of Unstrained Cycloalkanols.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c00662

Abstract: Herein, we report the enantioselective addition of remote alkyl radicals, generated from the ring opening of unstrained cycloalkanols by a proton-coupled electron transfer (PCET) process, to 2-acyl imidazoles previously coordinated to a rhodium-based chiral Lewis… read more here.

Keywords: alkyl radicals; addition remote; remote alkyl; enantioselective addition ... See more keywords
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Kinetic Isotope Effects and Hydrogen Tunnelling in PCET Oxidations of Ascorbate: New Insights into Aqueous Chemistry?

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Published in 2020 at "Molecules"

DOI: 10.3390/molecules25061443

Abstract: Recent experimental studies of kinetic isotope effects (KIE-s) and hydrogen tunnelling comprising three proton-coupled electron transfer (PCET) oxidations of ascorbate monoanion, (a) in aqueous reaction solutions, (b) in the mixed water-organic cosolvent systems, (c) in… read more here.

Keywords: isotope effects; pcet; chemistry; kinetic isotope ... See more keywords