Electronic Structure of Tetragonal Fe-Oxo Complexes Governs HAT vs PCET Mechanisms in C-H Oxidation.
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DOI: 10.1021/acs.inorgchem.5c01823
Abstract: Discerning hydrogen atom transfer (HAT) from proton-coupled electron transfer (PCET) mechanisms in C-H oxidation by biomimetic Fe-oxo complexes remains a longstanding challenge, with a central question being how the electronic structure and spin state of… read more here.
Keywords: pcet mechanisms; hat pcet; mechanisms oxidation; oxo ... See more keywords