1-D and 2-D phosphine coordination materials based on a palladium(II) PCP pincer metalloligand
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.09.025
Abstract: Abstract Ancillary functionalization of a PCP pincer ligand with para -carboxylic acids provides a simple route to the subsequent preparation of crystalline coordination polymers using pre -cyclometallated complexes as polymer building blocks. This synthetic strategy… read more here.
Keywords: coordination materials; coordination; pcp pincer; pcp ... See more keywords
Chiral Bis(Phospholane) PCP Pincer Complexes: Synthesis, Structure, and Nickel-Catalyzed Asymmetric Phosphine Alkylation
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00284
Abstract: A known ligand precursor, prepared by an improved method from 1,3-bis(bromomethylbenzene), a base, and (R,R)-2,5-dimethylphospholane-borane, was deprotected with DABCO and used to prepare chiral m-xylene-based PCP pincer complexes. Reaction with Ni(DME)Br2 and NEt3 gave square… read more here.
Keywords: pincer; nickel; bis phospholane; pcp pincer ... See more keywords
Synthesis and Reactivity of Group Six Metal PCP Pincer Complexes: Reversible CO Addition Across the Metal–Caryl Bond
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00447
Abstract: In the present study, Cr(III) complexes of the type trans-[Cr(PCPNEt-iPr)(solvent)Cl2] (solvent = CH3CN, THF), the Cr(0) complex [Cr(κ3P,CH,P-P(CH)PNEt-iPr)(CO)3] which features an η2-Caryl–H agostic bond as well as seven coordinate cationic chloro carbonyl Mo(II) and W(II)… read more here.
Keywords: pcpnet ipr; bond; across metal; metal ... See more keywords
Manganese and iron PCP pincer complexes - the influence of sterics on structure and reactivity.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02407h
Abstract: The syntheses of various manganese and iron PCP pincer complexes via a solvothermal oxidative addition methodology is described. Upon reacting [Mn2(CO)10] with the ligands (P(C-Br)PCH2-iPr) (1a) and (P(C-Br)PO-iPr) (1b), Mn(I) PCP pincer complexes [Mn(PCPCH2-iPr)(CO)3] (2a)… read more here.
Keywords: pincer; pcp pincer; reactivity; ipr ... See more keywords
Crystal structure of an iridium(III) complex of the [C(dppm)2] PCP pincer ligand system and its conjugate CH acid form
Sign Up to like & getrecommendations! Published in 2018 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989018004905
Abstract: The crystal structures of [IrIII(CO)(C(dppm)2-κ 3P,C,P′)ClH]Cl and [IrIII(CO)(CH(dppm)2-κ 3P,C,P′)ClH]Cl2 have been determined. Both complexes show a slightly distorted octahedral coordinated IrIII centre. The PCP pincer ligand system is arranged in a meridional manner. read more here.
Keywords: pcp pincer; pincer ligand; dppm; ligand system ... See more keywords