One-pot synthesis of a PCsp3P-type pincer complex via double C H palladation of a large chelate ring
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DOI: 10.1016/j.poly.2020.114415
Abstract: Abstract The diphosphine proligand R2P(CH2)5PR2 (R = i-Pr) reacts with PdCl2 or Pd(PhCN)2Cl2 in CH2Cl2 to give the 2:2 adduct trans-{µ-kP,kP′-R2P(CH2)5PR2}2Pd2Cl4 (1) featuring a 16-atom chelate ring, along with other uncharacterized species. Treating 1 with AgOTf or… read more here.
Keywords: type pincer; chelate ring; pcsp3p type; one pot ... See more keywords