Self-assembly, interlocking, interconversion and anion-binding catalysis in phenoxazine-based Pd2L4 and Pd4L8 coordination cages
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DOI: 10.1038/s41467-025-57876-6
Abstract: Interpenetration is a phenomenon frequently encountered in self-assembled Pd2L4-type coordination cages, while the mechanism of the interpenetration process remains unclear. Here we show the synthesis and solvent-mediated interconversion of highly soluble phenoxazine-based monomeric cage 1… read more here.
Keywords: pd2l4; coordination cages; phenoxazine based; interconversion ... See more keywords
Conformational control of Pd2L4 assemblies with unsymmetrical ligandsâ€
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DOI: 10.1039/c9sc05534g
Abstract: With increasing interest in the potential utility of metallo-supramolecular architectures for applications as diverse as catalysis and drug delivery, the ability to develop more complex assemblies is keenly sought after. Despite this, symmetrical ligands have… read more here.
Keywords: pd2l4 assemblies; metallo supramolecular; control pd2l4; pd2l4 ... See more keywords
Maximized axial helicity in a Pd2L4 cage: inverse guest size-dependent compression and mesocate isomerism
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DOI: 10.1039/d2sc06629g
Abstract: Helicity is an archetypal structural motif of many biological systems and provides a basis for molecular recognition in DNA. Whilst artificial supramolecular hosts are often helical, the relationship between helicity and guest encapsulation is not… read more here.
Keywords: mesocate; cage; maximized axial; helicity ... See more keywords