Neighbouring effects on catalytic epoxidation by Fe-cyclam in M2-PDIxCy complexes.
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DOI: 10.1039/d0dt03758c
Abstract: The unsymmetric PDIeCy ligand, featuring pyridinediimine and cylam sites, can be selectively metalated. Complementing the diiron compound, we have synthesized two heterobimetallic isomers, [ZnPDIFeCy(PDIeCy)(OTf)4] (3) and [FePDIZnCy(PDIeCy)(OTf)4] (4), and a dizinc complex, [Zn2(PDIeCy)(OTf)4] (5). Olefin… read more here.
Keywords: catalytic epoxidation; neighbouring effects; pdiecy otf; effects catalytic ... See more keywords