Phosphorus guiding palladium: [4 + 4] metallomacrocyclic PdII complex and self-assembly of heterometallic PdII/ZnII grid-type complex.
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DOI: 10.1039/d2dt01176j
Abstract: The reaction of heteroditopic ligand 1 featuring a hard pyridine-hydrazone-pyrimidine (N,N,N) site and a softer pyrimidine-hydrazone-phosphane (N,N,P) pocket with [Pd(CH3CN)4](OTf)2 in different metal-to-ligand ratios (M : L) gave the homobimetallic PdII complex [Pd2(1)(CH3CN)2](OTf)4 (2, M : L ratio 2 : 1),… read more here.
Keywords: assembly heterometallic; self assembly; pdii; heterometallic pdii ... See more keywords
A naphthalene-based heterobimetallic triazolylidene IrIII/PdII complex: regioselective to regiospecific C-H activation, tandem catalysis and a copper-free Sonogashira reaction.
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DOI: 10.1039/d2dt03508a
Abstract: Heterobimetallic complexes featuring mesoionic carbene (MIC) donor ligands are gaining enormous popularity in tandem catalysis owing to the combined action of two different metal centers during catalysis. A rare version of the heterobimetallic PdII/IrIII complex… read more here.
Keywords: regioselective regiospecific; naphthalene based; tandem catalysis; pdii ... See more keywords