Phosphorus guiding palladium: [4 + 4] metallomacrocyclic PdII complex and self-assembly of heterometallic PdII/ZnII grid-type complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01176j
Abstract: The reaction of heteroditopic ligand 1 featuring a hard pyridine-hydrazone-pyrimidine (N,N,N) site and a softer pyrimidine-hydrazone-phosphane (N,N,P) pocket with [Pd(CH3CN)4](OTf)2 in different metal-to-ligand ratios (M : L) gave the homobimetallic PdII complex [Pd2(1)(CH3CN)2](OTf)4 (2, M : L ratio 2 : 1),… read more here.
Keywords: assembly heterometallic; self assembly; pdii; heterometallic pdii ... See more keywords
A naphthalene-based heterobimetallic triazolylidene IrIII/PdII complex: regioselective to regiospecific C-H activation, tandem catalysis and a copper-free Sonogashira reaction.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03508a
Abstract: Heterobimetallic complexes featuring mesoionic carbene (MIC) donor ligands are gaining enormous popularity in tandem catalysis owing to the combined action of two different metal centers during catalysis. A rare version of the heterobimetallic PdII/IrIII complex… read more here.
Keywords: regioselective regiospecific; naphthalene based; tandem catalysis; pdii ... See more keywords
The unprecedented strong paratropic ring current of a bis-PdII complex of 5,10,23-trimesityl [28]heptaphyrin(1.1.0.0.1.0.0)
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc01909a
Abstract: Acid-catalyzed Friedel–Crafts-type cyclization of tetrapyrrolic BF2 complex 1 and α,α′-dibromotripyrrin 2 gave 5,10,23-trimesityl [28]heptaphyrin(1.1.0.0.1.0.0) BF2 complex 3BF2 as a stable and moderate antiaromatic macrocycle. Demetalation of 3BF2 with methanesulfonic acid followed by treatment with HCl… read more here.
Keywords: trimesityl heptaphyrin; paratropic ring; pdii complex; bis pdii ... See more keywords