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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03147
Abstract: Palladium-promoted acyl migration was observed in the reaction of (Z)-pent-2-en-4-yn-1-yl alkanoates in the presence of DBU to yield 2-(alkanoylmethyl)furan derivatives (2) in high yields. Compounds 2 then underwent oxidative decarbonylation to afford 2-acylfurans with O2…
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Keywords:
group shift;
acyl group;
pent alkanoates;
cyclization ... See more keywords