Exploring three stable penta-coordinated multinuclear Cu(II) bis(salamo)-based complexes
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120309
Abstract: Abstract Penta-coordinated homo-binuclear [Cu2(L)(CH3OH)]ClO4·CH3OH (1), [Cu2(L)(CH3CH2OH)]ClO4 (2) and homo-tetranuclear [{Cu2(HL)Cl(μ-Cl)}2]·2CHCl3 (3) complexes containing a symmetrical multi-halogen-substituted bis(salamo)-based ligand H3L have been successfully synthesized and characterized by elemental analyses, FT-IR and UV–Vis absorption spectroscopy, Hirshfeld surfaces… read more here.
Keywords: bis salamo; penta; salamo based; penta coordinated ... See more keywords
Penta-coordinated or -valent: the nature of the chemical bond of some Ti-C-Al compounds.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00164d
Abstract: Detailed DFT calculations of the published [CpTi(μ2-Me)(μ2-NPPh3)(μ5-C)(μ2-AlMe2)2(AlMe2)(AlMe3)] 1 revealed the triple-bond nature of the Ti-C bond and thus being a methide carbon with 5 surrounding ligands. This finding was further corroborated by the derivates [CpTi(μ2-Me)(μ2-NPPh3)(μ4-C)(μ2-AlMe2)2(AlMe2)]… read more here.
Keywords: alme2; coordinated valent; cpti npph3; penta coordinated ... See more keywords