Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species.
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DOI: 10.1021/acs.inorgchem.9b00447
Abstract: We previously reported that the tetraazamacrocyclic Schiff base complex [CoIII(CR14)(X)2] n+ (CR14 = 2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),2,11,13,15-pentaene, X = Cl ( n = 1) (1-Cl2) or H2O ( n = 3) (1-(H2O)2)) is a very efficient H2-evolving catalyst… read more here.
Keywords: catalyst; electron reduced; base complex; pentaaza macrocyclic ... See more keywords