Theoretical Design of Stable Pentacoordinate Boron Compounds
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DOI: 10.1021/acsomega.1c06415
Abstract: Through theoretical computations, we found that boron can form thermodynamically stable pentacoordinate compounds. Pentacoordinate boron (penta-B) is just hypercoordinate but not hypervalent because it forms only four covalent bonds, of which at least one is… read more here.
Keywords: design stable; stable pentacoordinate; theoretical design; pentacoordinate boron ... See more keywords
Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex.
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DOI: 10.1039/c9cc06610a
Abstract: A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The… read more here.
Keywords: pentacoordinate; relaxation; slow magnetic; magnetic relaxation ... See more keywords