Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Oxo-Bridged Dinuclear Cerium Complexes with Pentadentate Schiff-Base Ligands under a Dioxygen Atmosphere
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DOI: 10.1021/acscatal.8b01718
Abstract: Ionic mononuclear and neutral dinuclear complexes of cerium(III) 3-L1–3-L9 bearing a series of dianionic pentadentate Schiff-base ligands were synthesized, characterized, and used as catalysts for N-oxyl radical-free aerobic alcohol oxidation. Reactions of Ce(NO3)3·6H2O with o-tert-butyl-substituted… read more here.
Keywords: base ligands; cerium; pentadentate schiff; cerium complexes ... See more keywords