Synthesis and Characterization of Dibenzo[a,f]pentalene: Harmonization of the Antiaromatic and Singlet Biradical Character.
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DOI: 10.1021/jacs.7b05709
Abstract: Mesityl derivatives of the unknown dibenzopentalene isomer dibenzo[a,f]pentalene were synthesized. The molecular geometry and physical properties of dibenzo[a,f]pentalene were investigated. Dibenzo[a,f]pentalene combines a large antiaromatic and appreciable singlet open-shell character, properties not shared by well-known… read more here.
Keywords: pentalene; dibenzo pentalene; character; singlet ... See more keywords
Tuning the antiaromatic character and charge transport of pentalene-based antiaromatic compounds by substitution
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DOI: 10.1039/d1tc03156b
Abstract: Substituting electron-donating and electron-accepting substituents on antiaromatic pentalene cores can significantly tune the optical absorption, energy levels, antiaromaticity, and transistor switch-on behavior. read more here.
Keywords: charge transport; pentalene; transport pentalene; character charge ... See more keywords
Modular Approaches to Cyclopentanoids and their Heteroanalogs
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DOI: 10.1055/a-1288-8240
Abstract: Cyclopentanoids and their derivatives are interesting targets in synthetic organic chemistry due to their extensive applications in various branches of chemical sciences like pharmaceuticals, natural and non-natural products. In view of these applications, several synthetic… read more here.
Keywords: cyclopentane; synthesis; pentalene; system synthesis ... See more keywords